Macroporous poly(aromatic amine): Synthesis and film fabrication

Macroporous poly(aromatic amine): Synthesis and film fabrication
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大孔聚(芳香胺):合成和薄膜制造

DOI:
10.1016/j.colsurfa.2009.07.033
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发表时间:
2010
期刊:
Colloids and Surfaces A: Physicochemical and Engineering Aspects
影响因子:
--
通讯作者:
K. Ariga
K. Ariga
中科院分区:
--
文献类型:
--
作者:
Jonathan P. Hill;Michael V. Lee;Xiao;Ken Okamoto;Mathew R. Linford;K. Ariga

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合成了由1H, 2h -二氢嘧啶氧化而来的与聚(1,8-二氨基萘)相关的新型可溶聚合物,并发现形成了六方结构的大孔膜(大孔聚(芳香胺)),由呼吸图的形成而来。聚合物形成了有序的大孔膜,孔尺寸均匀,在0.2 ~ 1μm之间。聚合物还形成了其他结构,包括纳米纤维、微粒和中空膜状物体。
New soluble polymers derived from oxidation of 1H,2H-dihyroperimidines and related to poly(1,8-diaminonaphthalene) were synthesized and found to form hexagonally structured macroporous films (macroporous poly(aromatic amine)) derived from the formation of breath figures. The polymers formed well-ordered macroporous films with homogeneous hole sizes between 0.2 and 1μm. The polymers also formed other structures including nanofibers, microparticles and hollow membranous objects.
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