Guest-specific function of a flexible undulating channel in a 7,7,8,8-tetracyano-p-quinodimethane dimer-based porous coordination polymer
Guest-specific function of a flexible undulating channel in a 7,7,8,8-tetracyano-p-quinodimethane dimer-based porous coordination polymer
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DOI：
10.1021/ja073505z
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发表时间：
2007-09-12
影响因子：
15
通讯作者：
Kitagawa, Susumu
中科院分区：
文献类型：
--
作者：
Shimomura, Satoru;Horike, Satoshi;Kitagawa, Susumu
我们设计并合成了一种柔性多孔配位聚合物，它对苯和环己烷具有高度的选择性分离能力。波状通道为苯提供了合适的空间，主体骨架和客体分子之间的H-pi相互作用导致了这种高选择性。
We have designed and synthesized a flexible porous coordination polymer with highly selective capacity to separate benzene from cyclohexane. The undulating channel providing the suitable space for the benzene and the H-pi interaction between the host framework and the guest molecules result in this high selectivity.