PREPARATION AND CHARACTERIZATION OF

PREPARATION AND CHARACTERIZATION OF
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发表时间:
1996
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通讯作者:
Cecilia Paglier;M. Natoli;F. Trotta
Cecilia Paglier;M. Natoli;F. Trotta
中科院分区:
其他
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作者:
Cecilia Paglier;M. Natoli;F. Trotta

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制备了含有碳酸酯衍生物~-环糊精(~-CD)的PEEK1WC膜,并研究了它们对乙酸对硝基苯酯(PNPA)水解的催化行为。在恒定的底物浓度和恒定的渗透速率下,研究了不同平均~-CD碳酸酯取代度(DS)、固定~-CD碳酸酯的量和操作搅拌速度的影响。 ~-CD膜反应器的性能和生产率表明CD稳定性得到改善。
Membranes of PEEKlWC containing carbonate derivative ~-cyclodextrin (~-CD) have been prepared and their catalytic behaviour for the p-nitrophenylacetate (PNPA) hydrolysis has been investigated. The effect of different average degree of ~-CD carbonate substitution (DS), the amount of immobilized ~-CD carbonate and operating stirring speeds have been examined under a constant substrate concentration and constant permeation rate. The performance and productivity of the ~-CD membrane reactor indicate an improvement of CD stability.