Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis
Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis
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DOI：
10.1039/c5ra01826a
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发表时间：
2015-01-01
期刊：
影响因子：
3.9
通讯作者：
Akita, Munetaka
中科院分区：
文献类型：
--
作者：
Chinzei, Tatsuya;Miyazawa, Kazuki;Akita, Munetaka
本文报道了一种在有机光氧化还原催化剂[Acr（+）-Mes] ClO_4作用下，有机三氟硼酸盐和羧酸的1 e-氧化生成碳自由基的简单方法。该有机光催化方案适合于与缺电子烯烃形成自由基C-C键。
A simple generation method of carbon radicals via 1e-oxidation of organotrifluoroborates and carboxylic acids by the action of an organophotoredox catalyst, 9-mesityl-10-methylacridinium perchlorate ([Acr(+)-Mes]ClO4), has been developed. This organophotocatalytic protocol is amenable to radical C-C bond formation with electron-deficient olefins.