EFFECT OF SUBSTITUENTS ON STEREOSELECTIVITY OF ACID-CATALYZED HYDROLYSIS OF A SERIES OF ARYLOXIRANS - NEW APPLICATION OF HAMMETT EQUATION
EFFECT OF SUBSTITUENTS ON STEREOSELECTIVITY OF ACID-CATALYZED HYDROLYSIS OF A SERIES OF ARYLOXIRANS - NEW APPLICATION OF HAMMETT EQUATION
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DOI：
10.1039/c39740000712
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发表时间：
1974-01-01
影响因子：
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通讯作者：
MACCHIA, F
中科院分区：
文献类型：
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作者：
BATTISTINI, C;BALSAMO, A;MACCHIA, F
13个1-芳基氧化环己烯酸催化水解生成的顺反二醇的比值与σ ~+常数的相关性表明，在导致顺式产物的过渡态中存在较高程度的碳正离子特征。
Correlation of the logarithms of the ratios of cis to trans diols formed in the acid-catalysed hydrolysis of 13 1-arylcyclohexene oxides with the σ+ constants indicates that there is a higher degree of carbocationic character in the transition state leading to the cis-product.