Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin.

Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin.
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β-羟烷基铑卟啉异常环氧化物形成消除的机理研究。

DOI:
10.1039/b511974j
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发表时间:
2006
期刊:
Chemical communications (Cambridge, England)
影响因子:
--
通讯作者:
Groves,JohnT
Groves,JohnT
中科院分区:
--
文献类型:
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作者:
Han,Yuan-Zhang;Sanford,MelanieS;England,MichaelD;Groves,JohnT

文献摘要

相似文献

A new and remarkably facile sp3-C–O bond forming reaction of β-hydroxyalkyl Rh porphyrins to form epoxides has been discovered and its mechanism investigated.