POLARITY OF VAN DER WAALS MOLECULES

POLARITY OF VAN DER WAALS MOLECULES
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范德华分子的极性

DOI:
10.1002/chin.197409002
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发表时间:
1973
期刊:
ChemInform
影响因子:
--
通讯作者:
W. Klemperer
W. Klemperer
中科院分区:
--
文献类型:
--
作者:
S. Novick;P. Davies;T. Dyke;W. Klemperer

文献摘要

被引文献

相似文献

用分子束电偏转的方法定性地测量了一些松散结合的络合物的极性。观察到以下物种为极性:ArNO、ArHCl、NeDCl、XeHCl。在观察到的非极性物种中,ArBF/sub3/,KrBF/sub3/,(NO)/sub2/,(HCl)/sub2/,BF/sub3/no,BF/sub3/CO,(CO/sub2/)/sub2/,N/sub2/0/sub2/,NeHCl,COH/sub2/,(BF/sub3/)/sub3/,(BF/sub3/)/sub4/,(BF/SUB 3/)/SUB 4/。这些结果的结构解释,以及一些初步的射频光谱学,被提出。
The polarity of a number of loosely bound complexes is qualitatively measured by molecular beam electric deflection. The following species are observed as polar: ArNO, ArHCl, NeDCl, XeHCl. ArBF/sub 3/, KrBF/sub 3/, (NO)/sub 2/, (HCl)/sub 2/, BF/sub 3/NO, BF/sub 3/CO, (CO/sub 2/)/sub 2/, Among the species observed to be nonpolar are: (NO)/sub 3/, (NO)/sub 4/, N/sub 2/0/sub 2/, NeHCl, COH/sub 2/, (BF/sub 3)/sub 3/, (BF/sub 3/)/sub 4/, (BF/ sub 3/)/sub 4/. Structural interpretations of these results, together with some preliminary radiofrequency spectroscopy, are presented.