High-resolution inner-shell spectroscopies of free atoms and molecules using soft-x-ray beamlines at the third-generation synchrotron radiation sources

High-resolution inner-shell spectroscopies of free atoms and molecules using soft-x-ray beamlines at the third-generation synchrotron radiation sources
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DOI:
10.1088/0953-4075/36/4/201
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发表时间:
2003-02
期刊:
Journal of Physics B
影响因子:
--
通讯作者:
K. Ueda
K. Ueda
中科院分区:
其他
文献类型:
--
作者:
K. Ueda

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本文综述了在第三代同步辐射装置软x射线光束线上安装的高分辨率软x射线单色器用于自由原子和分子内壳层光谱研究的现状。光束线和终端站致力于原子和分子内壳光谱和各种类型的实验技术,如离子产额光谱,共振光电子能谱和多重符合动量成像,进行了说明。作为第三代同步辐射光源原子分子内壳层光谱学的例子,讨论了在日本SPring-8的27 SU光束线上获得的Ne的K壳层激发、H_2O和CO_2的O K壳层激发、CO_2的C K壳层激发和电离以及BF_3的B K壳层激发的实验结果。
This article reviews the current status of inner-shell spectroscopies of free atoms and molecules using high-resolution soft-x-ray monochromators installed in the soft-x-ray beamlines at the third-generation synchrotron radiation facilities. Beamlines and endstations devoted to atomic and molecular inner-shell spectroscopies and various types of experimental techniques, such as ion yield spectroscopy, resonant photoemission spectroscopy and multiple-coincidence momentum imaging, are described. Experimental results for K-shell excitation of Ne, O K-shell excitation of H2O and CO2, C K-shell excitation and ionization of CO2 and B K-shell excitation of BF3, obtained at beamline 27SU of SPring-8 in Japan, are discussed as examples of atomic and molecular inner-shell spectroscopies using the third-generation synchrotron radiation sources.