A highly porous rht-type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities
A highly porous rht-type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities
复制标题
一种高度多孔的 rht 型酰胺官能化金属有机框架,表现出巨大的 CO2 吸收能力
DOI:
10.1039/c6cc06734d
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发表时间:
2016
影响因子:
4.9
通讯作者:
Duan Jingui
中科院分区:
文献类型:
--
作者:
Zheng Baishu;Wang Hang;Wang Zhaoxu;Ozaki Noriaki;Hang Cheng;Luo Xin;Huang Lu;Zeng Wenjiang;Yang Ming;Duan Jingui
A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2 g−1, and a large CO2 uptake capability (38.9 mmol g−1 under 36 bar) with an excellent selectivity of CO2/CH4 (7.3) and CO2/N2 (32.5) at 273 K.