A highly porous rht-type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities

A highly porous rht-type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities
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一种高度多孔的 rht 型酰胺官能化金属有机框架,表现出巨大的 CO2 吸收能力

DOI:
10.1039/c6cc06734d
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发表时间:
2016
影响因子:
4.9
通讯作者:
Duan Jingui
Duan Jingui
中科院分区:
化学2区
文献类型:
--
作者:
Zheng Baishu;Wang Hang;Wang Zhaoxu;Ozaki Noriaki;Hang Cheng;Luo Xin;Huang Lu;Zeng Wenjiang;Yang Ming;Duan Jingui

文献摘要

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合成了一种具有(3,24)连接rht型网络的新型高孔酰胺功能化MOF (HNUST-5),并利用粉末x射线衍射对其结构进行了表征。HNUST-5具有较高的BET表面积(3643 m2 g−1)和较大的CO2吸收能力(36 bar下38.9 mmol g−1),在273 K下具有良好的CO2/CH4(7.3)和CO2/N2(32.5)选择性。
A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2 g−1, and a large CO2 uptake capability (38.9 mmol g−1 under 36 bar) with an excellent selectivity of CO2/CH4 (7.3) and CO2/N2 (32.5) at 273 K.