O-ACYLHYDROXYLAMINES .2. O-MESITYLENESULFONYL-HYDROXYLAMINE, O-PARA-TOLUENESULFONYL-HYDROXYLAMINE AND O-MESITOYLHYDROXYLAMINE
O-ACYLHYDROXYLAMINES .2. O-MESITYLENESULFONYL-HYDROXYLAMINE, O-PARA-TOLUENESULFONYL-HYDROXYLAMINE AND O-MESITOYLHYDROXYLAMINE
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DOI：
10.1021/ja01497a037
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发表时间：
1960-01-01
影响因子：
15
通讯作者：
CARPINO, LA
中科院分区：
文献类型：
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作者：
CARPINO, LA
用氢氟酸和高氯酸裂解相应的n -丁基氨基甲酸乙酯，制备了-三亚甲磺酰和对甲苯磺酰羟胺。通过(a)碘量分析，(b)与丙酮反应得到相应的o -磺酰基肟，(c)红外检测确定了o -磺酰基羟胺的结构。同样，以ŋ-butyl为原料制备了o -三甲氧基羟胺。邻甲氧基羟胺与二苄胺反应得到1,1 -二苄肼。
-Mesitylenesulfonyl-and Op-toluenesulfonylhydroxylamine have been prepared by the hydrofluoric acid and perchloric acid cleavages of the corresponding-butyl N-arenesulfonoxycarbamates. The structures of the O-arenesulfonylhydroxyl-amines were established by (a) iodometric analysis,(b) reaction with acetone which gave the corresponding O-sulfonylacet-oximes and (c) infrared examination. O-Mesitoylhydroxylamine was prepared similarly from ŋ-butyl N-mesitoyloxycar-bamate. Reaction of O-mesitoylhydroxylamine with dibenzylamine gave 1, 1-dibenzylhydrazine.