A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields.

A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields.
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DOI:
10.1002/anie.201106748
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发表时间:
2012-03-05
影响因子:
16.6
通讯作者:
Raymond, Kenneth N.
Raymond, Kenneth N.
中科院分区:
化学1区
文献类型:
--
作者:
Law, Ga-Lai;Pham, Tiffany A.;Xu, Jide;Raymond, Kenneth N.

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多功能八齿TIAM配体在水中与镧系元素(钐、铕、铽、镝、钬)形成具有高量子产率的配合物。这种配体是一种高效的敏化剂,并且如对钬配合物的X射线衍射研究所示,它还能保护金属中心免受溶剂猝灭。
The versatile octadentate TIAM ligand forms lanthanide (Sm, Eu, Tb, Dy, Ho) complexes with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.
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