Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts.
Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts.
复制标题
探索原位生成的纳米粒子作为可持续氧化催化剂的起源。
DOI：
10.1039/c3dt50606a
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发表时间：
2013
影响因子：
4
通讯作者：
R. Raja
中科院分区：
文献类型：
--
作者：
C. Hinde;S. van Aswegen;G. Collins;Justin D. Holmes;T. S. Andy Hor;R. Raja
A novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-chemical characterisation, in combination with in-depth kinetic analysis have afforded profound insights into the nature of the active site for facilitating structure-property correlations.
