Heat- or Water-Driven Malleability in a Highly Recyclable Covalent Network Polymer
Heat- or Water-Driven Malleability in a Highly Recyclable Covalent Network Polymer
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DOI：
10.1002/adma.201400317
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发表时间：
2014-06-18
影响因子：
29.4
通讯作者：
Zhang, Wei
中科院分区：
文献类型：
--
作者：
Taynton, Philip;Yu, Kai;Zhang, Wei
通过亚胺化学制备了一种可通过水或热进行二次加工的无催化剂可延展网络聚合物。这种材料从细小的粉末回收为粘性固体，经过几代后具有100%的回收效率。它还在常温下仅使用水进行再加工，因此可能导致材料的能源中性绿色加工。
A catalyst-free malleable network polymer that can be reprocessed by application of either water or heat is prepared through imine chemistry. This material is recycled from a fine powder to a coherent solid with >100% recycling efficiency through several generations. It is also reprocessed at ambient temperature using only water, thus potentially leading to energy-neutral green processing of the material.