Zeolite-like copper iodide framework with new 6(6) topology.
Zeolite-like copper iodide framework with new 6(6) topology.
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DOI：
10.1021/ic061163c
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发表时间：
2007-01
影响因子：
4.6
通讯作者：
M. Bi;Guanghua Li;Y. Zou;Zhan Shi;S. Feng
中科院分区：
文献类型：
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作者：
M. Bi;Guanghua Li;Y. Zou;Zhan Shi;S. Feng
我们已经描述了一种前所未有的三维沸石状碘化铜由Cu_4 I_4（DABCO）_4（DABCO = 1，4-二氮杂双环[2.2.2]辛烷）超四面体单元构建。该化合物形成具有新的6（6）拓扑的四连通网络。它的结构揭示了一维通道沿着[001]方向，和框架显示有趣的自穿透。标题化合物在室温下呈固态发光。
We have described an unprecedented three-dimensional zeolite-like copper iodide constructed from Cu4I4(DABCO)4 (DABCO = 1,4-diazabicyclo[2.2.2]octane) supertetrahedron units. This compound forms a four-connected network with new 6(6) topology. Its structure reveals one-dimensional channels along the [001] direction, and the framework displays interesting self-penetration. The title compound shows photoluminescence at room temperature in the solid state.