μ-Acetato-κO:O'-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa-azatri-cyclo-[27.3.1.1]tetra-triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca-ene-33,34-diolato-κN,N,N,O,O:N,N,N,O,O]dinickel(II) per-chlorate acetonitrile disolvate.
μ-Acetato-κO:O'-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa-azatri-cyclo-[27.3.1.1]tetra-triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca-ene-33,34-diolato-κN,N,N,O,O:N,N,N,O,O]dinickel(II) per-chlorate acetonitrile disolvate.
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μ-乙酰基-μO:O-[7,23-二苄基-15,31-二氯-3,7,11,19,23,27-六氮杂三环-[27.3.1.1]tetra-triconta-1
DOI：
10.1107/s1600536807061399
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发表时间：
2007
期刊：
影响因子：
--
通讯作者：
Pan,Zhi-Quan
中科院分区：
文献类型：
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作者：
Kong,Juan;Zhou,Hong;Pan,Zhi-Quan
标题化合物[Ni2(C42H46Cl2N6O2)(C2H3O2)]ClO4·2CH3CN由2，6-二甲酰基-4-氯苯酚与N，N-二(氨基丙基)苯甲胺在NiII离子存在下缩合而成。该配体是一个28元大环，具有两个相同的吊臂。Ni原子的配位几何构型均为八面体。两个镍原子由两个大环配体和一个醋酸酯配体上的两个酚氧原子桥联，Ni⋯Ni距离为3.147 (4) ä。
The title complex, [Ni2(C42H46Cl2N6O2)(C2H3O2)]ClO4·2CH3CN, was synthesized by condensation of 2,6-diformyl-4-chlorophenol with N,N-bis(aminopropyl)benzylamine in the presence of NiII ions. The ligand is a 28-membered macrocycle with two identical pendant arms. The coordination geometries of the Ni atoms are both octahedral. The two Ni atoms are bridged by two phenolate O atoms of the macrocyclic ligand and one acetate ligand, with an Ni⋯Ni distance of 3.147 (4) Å.