Structural chemistry of uranium phosphonates

Structural chemistry of uranium phosphonates
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磷酸铀的结构化学

DOI:
10.1016/j.ccr.2015.05.010
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发表时间:
2015-11
影响因子:
20.6
通讯作者:
Sun, Zhong-Ming
Sun, Zhong-Ming
中科院分区:
化学1区
文献类型:
--
作者:
Yang, Weiting;Parker, T. Gannon;Sun, Zhong-Ming

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Uranium phosphonates, an important class of actinide-organic coordination polymers, exhibit an exceptionally diverse and broad range of crystal structures. A variety of structure topologies have been identified for hexavalent uranium phosphonates, including cage clusters, chains, ribbons and tubes, sheets, and three-dimensional frameworks. In contrast, only a handful of tetravalent uranium phosphonates are known. This review presents a comprehensive account of the crystal structures of uranium phosphonates and the various building units (e.g.discrete monomers, polymeric units, infinite chains, and sheets) that result from the numerous coordination modes of phosphonate ligands with uranium.
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