Organocatalyzed enantioselective Michael additions of nitroalkanes to enones by using primary-secondary diamine catalysts.

Organocatalyzed enantioselective Michael additions of nitroalkanes to enones by using primary-secondary diamine catalysts.
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DOI:
10.1039/c002552f
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发表时间:
2010-06
影响因子:
4.9
通讯作者:
Yingquan Yang;Xin-Kuan Chen;Hua Xiao;Wen Liu;Gang Zhao
Yingquan Yang;Xin-Kuan Chen;Hua Xiao;Wen Liu;Gang Zhao
中科院分区:
化学2区
文献类型:
--
作者:
Yingquan Yang;Xin-Kuan Chen;Hua Xiao;Wen Liu;Gang Zhao

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伯仲二胺是硝基烷烃不对称加成到烯酮上的有效有机催化剂,使迈克尔加成物具有优异的产率和对映选择性。
Primary-secondary diamines perform as efficient organocatalysts for the asymmetric addition of nitroalkanes to enones, giving the Michael adducts with excellent yields and enantioselectivities.