Reactions of the Tridentate and Tetradentate Amine Ligands di-(2-picolyl)(N-ethyl)amine and 2,5-Bis-(2-pyridylmethyl)-2,5 diazohexane with Technetium Nitrosyl Complexes.
Reactions of the Tridentate and Tetradentate Amine Ligands di-(2-picolyl)(N-ethyl)amine and 2,5-Bis-(2-pyridylmethyl)-2,5 diazohexane with Technetium Nitrosyl Complexes.
复制标题
三齿和四齿胺配体二-(2-吡啶基)(N-乙基)胺和2,5-双-(2-吡啶基甲基)-2,5重氮己烷与亚硝基锝配合物的反应。
DOI：
10.1016/j.ica.2011.04.002
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发表时间：
2011
影响因子：
2.8
通讯作者：
Jones,AG
中科院分区：
文献类型：
--
作者：
Nicholson,T;Mahmood,A;Limpa-Amara,N;Salvarese,N;Takase,MK;Müller,P;Jones,AG
The reaction of the Tc(II) nitrosyl complex (Bu4N)[Tc(NO)Cl4] with di-(2-picolyl)(NEt)amine in methanol yields the neutral complex [Tc(NO)Cl(py-N(Et)-py)]. The reaction of the Tc(I) nitrosyl complex [Tc(NO)Cl2(HOMe)(PPh3)2] with this tridentate ligand yields cationic [Tc(NO)Cl(py-N(Et)-py)(PPh3)]Cl. These two complexes have been structurally characterized. The reaction of [Tc(NO)Cl2(HOMe)(PPh3)2] with the tetradentate ligand 1,4-bis-(2-pyridylmethyl)-1,4-diazobutane yields a mixture of products including cationic [Tc(NO)Cl(py-NH-NH-py)]Cl and cationic [Tc(NO)Cl(PPh3)(py-NH-NH∼py)]Cl, with a pyridyl terminus left dangling.
