Transition-metal-catalyzed regioselective aroyl- and trifluoro-acetylthiolation of alkynes using thioesters.
Transition-metal-catalyzed regioselective aroyl- and trifluoro-acetylthiolation of alkynes using thioesters.
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DOI：
10.1039/b900492k
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发表时间：
2009-05
影响因子：
4.9
通讯作者：
Yasunori Minami;H. Kuniyasu;Kiyoshi Miyafuji;N. Kambe
中科院分区：
文献类型：
--
作者：
Yasunori Minami;H. Kuniyasu;Kiyoshi Miyafuji;N. Kambe
Intermolecular CO-retained carbothiolation of alkynes using thioesters took place to afford beta-SR substituted enone derivatives; the choice of catalyst (Pd(dba)(2)-dppe) and the introduction of a CF(3) group into the thioesters are the key to achieving the transformation.
