Brown grease pyrolysis under pressure: Extending the range of reaction conditions and hydrocarbon product distributions

Brown grease pyrolysis under pressure: Extending the range of reaction conditions and hydrocarbon product distributions
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棕色油脂在压力下热解:扩大反应条件和碳氢化合物产品分布的范围

DOI:
10.1016/j.fuel.2020.119782
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发表时间:
2021
期刊:
影响因子:
7.4
通讯作者:
Xiao, Dequan
Xiao, Dequan
中科院分区:
工程技术1区
文献类型:
--
作者:
Pratt, Lawrence M.;Kim, Jihyun;Lo, Ho-Yin;Xiao, Dequan

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在加压反应器中进行了棕色润滑脂热解制烃产品的研究。与我们以前在常压下的工作相比,可以实现更高的反应温度。这导致了更短的反应时间,减少了不需要的酮副产物的形成,并提高了最有价值的轻烃产品的比例。然而,更高的温度确实增加了气体产品的比例,但牺牲了液体产品的比例。主要的液体产物是从庚烷到十七烷的烷烃,还有少量的环烷烃,在某些情况下,还有芳香族化合物。
Pyrolysis of brown grease to hydrocarbon products was performed in a pressure reactor. Compared to our previous work at atmospheric pressure, higher reaction temperatures could be achieved. These resulted in shorter reaction times, reduced formation of undesirable ketone byproducts, and a higher percentage of the most valuable light hydrocarbon products. Higher temperatures did, however, increase the percentage of gas products at the expense of liquid products. The major liquid products are alkanes ranging from heptane to heptadecane, with smaller amounts of cycloalkanes, and in some cases, aromatic compounds.
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