Structural Implication of Oxoammonium Cations for Reversible Organic One-electron Redox Reaction to Nitroxide Radicals
Structural Implication of Oxoammonium Cations for Reversible Organic One-electron Redox Reaction to Nitroxide Radicals
复制标题
氧铵阳离子对氮氧自由基可逆有机单电子氧化还原反应的结构意义
DOI：
10.1246/cl.2007.866
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发表时间：
2007
影响因子：
1.6
通讯作者：
H. Nishide
中科院分区：
文献类型：
--
作者：
Yasunori Yonekuta;K. Oyaizu;H. Nishide
氮氧自由基的结构和电化学行为表明，它们的快速和可逆的氧化还原反应不仅是基于它们的化学稳定性，但也对增加的sp2字符的氮，这是中间的纯sp2和sp3氮的氧代铵阳离子和胺，分别。
Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.