Role of the B '-site metal ion in the framework structures and dielectric transitions in host-guest type cyanometalates (HIm)(2)[B ' Co(CN)(6)] (HIm = imidazolium cation)
Role of the B '-site metal ion in the framework structures and dielectric transitions in host-guest type cyanometalates (HIm)(2)[B ' Co(CN)(6)] (HIm = imidazolium cation)
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DOI：
10.1039/c9ce01739a
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发表时间：
2020
期刊：
影响因子：
3.1
通讯作者：
Zhang Wen
中科院分区：
文献类型：
--
作者：
Shi Chao;Gong Zhi-Xin;Wang Qin-Wen;Han Xiang-Bin;Zhang Wen
在一系列六氰钴酸盐基有机-无机杂化化合物（HIm）2[B′Co（CN）6]（HIm =咪唑阳离子）中，B′位碱金属离子（B′ = Li，Na，K，Rb）对客体骨架结构的变化和动力学行为起着关键作用.结果，相关的体介电性质也改变。
The B′-site alkali metal ion (B′ = Li, Na, K, and Rb) in a series of hexacyanocobaltate-based organic–inorganic hybrid compounds (HIm)2[B′Co(CN)6] (HIm = imidazolium cation) plays a key role in the change of the framework structures and the dynamic behaviours of the guest. As a result, the associated bulk dielectric properties are also changed.