Homogeneous Activation of Molecular Hydrogen by Four-, Five-, and Six-Coordinate Transition Metal Complexes
Homogeneous Activation of Molecular Hydrogen by Four-, Five-, and Six-Coordinate Transition Metal Complexes
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四、五、六配位过渡金属配合物对氢分子的均相活化
DOI：
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发表时间：
1964
期刊：
影响因子：
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通讯作者：
L. Vaska
中科院分区：
文献类型：
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作者：
L. Vaska
已经发现某些二价钌（1）和锇（1，2）以及三价和单价铱（3，4）的中性络合物在正常条件下活化溶液中的分子氢。这些反应是相当感兴趣的，因为它们允许比较具有不同配位数和形式氧化态的金属络合物的氢活化特性，这两种特性被认为是决定氢的催化活化的重要因素。
Certain neutral complexes of bivalent ruthenium (1) and osmium (1, 2), and tervalent and univalent iridium (3, 4) have been discovered to activate molecular hydrogen in solution at normal conditions. These reactions are of considerable interest because they permit comparison of hydrogen-activating characteristics of metal complexes with different coordination numbers and formal oxidation states, two properties which are believed to represent important factors in determining catalytic activation of hydrogen.