Oligocyclic ladder polysiloxanes: Alternative synthesis by oxidation
Oligocyclic ladder polysiloxanes: Alternative synthesis by oxidation
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DOI：
10.1021/om049324c
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发表时间：
2005-02-14
期刊：
影响因子：
2.8
通讯作者：
Matsumoto, H
中科院分区：
文献类型：
--
作者：
Unno, M;Tanaka, R;Matsumoto, H
用间氯过苯甲酸（mCPBA）氧化梯形聚硅氧烷，合成了一系列梯形聚硅氧烷，并对其结构进行了测定。所有Si-Si键的完全氧化用大量过量的mCPBA使用长反应时间完成。
A series of ladder polysiloxanes was prepared by oxidation of the corresponding ladder polysilanes with mCPBA (m-chloroperbenzoic acid), and their structures were determined. Complete oxidation of all Si-Si bonds was accomplished with a large excess of mCPBA using long reaction times.