Slow magnetization relaxation in unprecedented Mn(III)4Dy(III)3 and Mn(III)4Dy(III)5 clusters from the use of N-salicylidene-o-aminophenol.
Slow magnetization relaxation in unprecedented Mn(III)4Dy(III)3 and Mn(III)4Dy(III)5 clusters from the use of N-salicylidene-o-aminophenol.
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DOI：
10.1021/ic302505p
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发表时间：
2013-01
影响因子：
4.6
通讯作者：
Dimitris I. Alexandropoulos;Tu N. Nguyen;L. Cunha-Silva;Theodoros F. Zafiropoulos;A. Escuer;G. Christou
中科院分区：
文献类型：
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作者：
Dimitris I. Alexandropoulos;Tu N. Nguyen;L. Cunha-Silva;Theodoros F. Zafiropoulos;A. Escuer;G. Christou
N-水杨醛邻氨基苯酚首次应用于3D/4F化学中，得到了具有前所未有的金属拓扑结构和化学计量比的Mn(III)(4)Dy(III)(5)和Mn(III)(4)Dy(III)(3)团簇；这两个化合物都显示出表明单分子磁体慢磁化驰豫的异相信号。
The first use of N-salicylidene-o-aminophenol in 3d/4f chemistry has led to Mn(III)(4)Dy(III)(5) and Mn(III)(4)Dy(III)(3) clusters with unprecedented metal topologies and stoichiometries; both compounds exhibit out-of-phase signals indicative of the slow magnetization relaxation of a single-molecule magnet.