Atomic shielding constants
Atomic shielding constants
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DOI：
10.1103/physrev.36.57
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发表时间：
1930-07-01
期刊：
影响因子：
--
通讯作者：
Slater, JC
中科院分区：
文献类型：
--
作者：
Slater, JC
类似于齐纳的方法，从Li到F的原子，简单的规则，建立近似解析原子波函数的所有原子，在任何阶段的电离。这些都适用于X射线的水平，大小的原子和离子，抗磁化率等与铁磁性，它表明，如果这真的取决于存在的不完整的壳内的原子，而远离晶体，那么金属最有可能显示它将是铁，钴，镍，合金锰和铜（Heusler合金）。
In analogy with the method of Zener for the atoms from Li to F, simple rules are set up giving approximate analytic atomic wave functions for all the atoms, in any stage of ionization. These are applied to x-ray levels, sizes of atoms and ions, diamagnetic susceptibility, etc. In connection with ferromagnetism it is shown that if this really depends on the existence of incomplete shells within the atoms, rather far apart in the crystal, then the metals most likely to show it would be Fe, Co, Ni, and alloys of Mn and Cu (Heusler alloys).