Photomediated RAFT step-growth polymerization with maleimide monomers
Photomediated RAFT step-growth polymerization with maleimide monomers
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DOI：
10.1039/d2py01166b
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发表时间：
2022-10-14
影响因子：
4.6
通讯作者：
You, Wei
中科院分区：
文献类型：
--
作者：
Clouthier, Samantha Marie;Tanaka, Joji;You, Wei
采用基于三硫代碳素的CTA和马来酰亚胺单体，在有光催化剂和没有光催化剂的情况下进行了光催化RAFT步长聚合。在无催化剂的条件下，在蓝光和绿光的照射下，聚合反应以可观的速度进行，在ZnTPP存在下，聚合反应扩展到红光。
Photomediated RAFT step-growth polymerization was performed with and without the presence of a photocatalyst using a trithiocarbonate-based CTA and a maleimide monomer. Under catalyst-free conditions, the polymerization proceeded with an appreciable rate under irradiation with blue and green light, which was extended to red light in the presence of ZnTPP.