Crystal structure and electrical properties of κ‐((S,S)‐DMBEDT–TTF)2ClO4
Crystal structure and electrical properties of κ‐((S,S)‐DMBEDT–TTF)2ClO4
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κ-((S,S)-DMBEDT-TTF)2ClO4 的晶体结构和电学性质
DOI：
10.1002/adma.19920040106
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发表时间：
1992
影响因子：
29.4
通讯作者：
G. Rihs
中科院分区：
文献类型：
--
作者：
J. Zambounis;Carl W. Mayer;Kurt Hauenstein;B. Hilti;W. Hofherr;Jurgen Pfeiffer;M. Bürkle;G. Rihs
对标题化合物的研究表明，手性分子体系中存在超导性。这项工作是最近基于不对称分子的有机超导体研究的重要延伸，它表明，在3k和5kbar时，电阻率会发生突然但不完全的损失（以500倍的速度）。这种行为和晶体填充基序都表明这种转变具有超导性质。
The existence of superconductivity in chiral molecular systemsis suggested by studies of the title compound. The work, which is an important extension of studies of recently organic superconductors based on unsymmetrical molecules, shows that a sudden, but incomplete loss of resistivity (by a factor of 500) takes place at 3 K and 5 kbar. Both this behavior and the crystal‐packing motif suggest that the transition is of a superconducting nature.