Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands
Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands
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DOI：
10.1021/acs.inorgchem.9b01340
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发表时间：
2019-07-15
影响因子：
4.6
通讯作者：
Nishibayashi, Yoshiaki
中科院分区：
文献类型：
--
作者：
Ashida, Yuya;Arashiba, Kazuya;Nishibayashi, Yoshiaki
我们已经发现了使用简单的和市售的单齿和双齿膦作为辅助配体，以简单和方便的程序，钯催化的氨形成。由[MoI 3（THF）（3）]和相应的膦如PMePh 2和1，5-双（二苯基膦基）戊烷原位生成的钼络合物有效地用于氨的形成。
We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)(3)] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.