Chiroptical induction with prism[5]arene alkoxy-homologs
Chiroptical induction with prism[5]arene alkoxy-homologs
复制标题
使用棱镜[5]芳烃烷氧基同系物进行手性光学感应
DOI：
10.1039/d2cc05690a
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发表时间：
2022
影响因子：
4.9
通讯作者：
Yang Cheng
中科院分区：
文献类型：
--
作者：
Liang Xiaotong;Shen Yanling;Zhou Dayang;Ji Jiecheng;Wang Hongtao;Zhao Ting;Mori Tadashi;Wu Wanhua;Yang Cheng
棱柱[5]芳烃与氨基酸衍生物的络合物显示缔合常数高达107 M−1，显著的CD与高达0.8 × 10−2的gabs和CPL与2 × 10−3的glum。建立了绝对构型-CD信号相关性。随着取代基的不同，圆二色性光谱有明显的变化。
The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 107 M−1, significant CD with gabs of up to 0.8 × 10−2 and CPL with glum of 2 × 10−3. The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with the substituents on the prism[5]arenes.