Direct four-electron reduction of O2 to H2O on TiO2 surfaces by pendant proton relay.

Direct four-electron reduction of O2 to H2O on TiO2 surfaces by pendant proton relay.
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DOI:
10.1002/anie.201304481
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发表时间:
2013-09
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通讯作者:
Hua Sheng;Hongwei Ji;Wanhong Ma;Chuncheng Chen;Jincai Zhao
Hua Sheng;Hongwei Ji;Wanhong Ma;Chuncheng Chen;Jincai Zhao
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作者:
Hua Sheng;Hongwei Ji;Wanhong Ma;Chuncheng Chen;Jincai Zhao

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本文讨论了一项研究,该研究显示了悬挂式质子继电器(聚质酸)在直接氧(O2)在二氧化钛(TiO2)表面还原途径上的使用。结果表明,在相同的氢幂(PH)条件下,加入磷酸盐可以提高苯甲酸(BA)的光催化降解率。它补充说,研究中显示的表面悬挂质子继电器的作用可用于氧还原反应(ORR)的设计。
The article discusses a study which shows the use of pendant proton relays (polyprotic acids) in the direct oxygen (O2) on a titanium oxide (TiO2) surface reduction pathway. It states that benzoic acid's (BA) photocatalytic degradation rate was seen to improved after adding phosphate at similar power of hydrogen (pH) value. It adds that the role of surface pendant proton relays shown in the study may be used in the design of oxygen reduction reaction (ORR).