Enzymatic synthesis and post-functionalization of two-dimensional crystalline cellulose oligomers with surface-reactive groups.
Enzymatic synthesis and post-functionalization of two-dimensional crystalline cellulose oligomers with surface-reactive groups.
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DOI：
10.1039/c5cc04378f
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发表时间：
2015-07
影响因子：
4.9
通讯作者：
Yusuke Yataka;Toshiki Sawada;T. Serizawa
中科院分区：
文献类型：
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作者：
Yusuke Yataka;Toshiki Sawada;T. Serizawa
二维纳米材料因其独特的结构和物理化学性质而受到广泛关注。本文中，我们通过酶促反应合成了具有表面反应性叠氮基团的2D结晶纤维素低聚物，并通过铜（i）催化的Huisgen环加成反应用1-乙炔基芘将其共价后官能化。
Two-dimensional (2D) nanomaterials have gained considerable attention due to their unique structural and physicochemical properties. Herein, we synthesized 2D crystalline cellulose oligomers with surface-reactive azide groups through enzymatic reactions and covalently post-functionalized them with 1-ethynyl pyrene through copper(i)-catalyzed Huisgen cycloaddition reactions.