Reversible Hydrogen Storage in Hydrogel Clathrate Hydrates
Reversible Hydrogen Storage in Hydrogel Clathrate Hydrates
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DOI：
10.1002/adma.200803402
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发表时间：
2009-06
影响因子：
29.4
通讯作者：
F. Su;C. Bray;Benjamin O. Carter;G. Overend;C. Cropper;J. Iggo;Y. Khimyak;A. Fogg;A. Cooper
中科院分区：
文献类型：
--
作者：
F. Su;C. Bray;Benjamin O. Carter;G. Overend;C. Cropper;J. Iggo;Y. Khimyak;A. Fogg;A. Cooper
使用廉价的水凝胶作为支持显着提高H2包合动力学和容量的THF-H2O笼形水合物相对于散装解决方案的证明。聚合物水凝胶引起显着的速率和容量增强氢笼形物的形成相对于未混合的散装系统，表明潜在的加速气体存储动力学的笼形物为基础的技术。
The use of inexpensive hydrogels as supports to significantly improve H2 enclathration kinetics and capacities in THF–H2O clathrate hydrate with respect to bulk solutions is demonstrated. Polymer hydrogels give rise to significant rate and capacity enhancements for hydrogen clathrate formation with respect to unmixed bulk systems, suggesting potential for accelerated gas-storage kinetics in clathrate-based technologies.