A simple and inexpensive microfluidic electrolysis cell
A simple and inexpensive microfluidic electrolysis cell
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DOI：
10.1016/j.electacta.2011.01.036
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发表时间：
2011-04-15
影响因子：
6.6
通讯作者：
Underwood, Toby J.
中科院分区：
文献类型：
--
作者：
Kuleshova, Jekaterina;Hill-Cousins, Joseph T.;Underwood, Toby J.
介绍了一种基于廉价材料和制造工艺的单通道微流控电解槽。用Fe(CN)(6)(3-)/Fe(CN)(6)(4-)对的电化学性质表征了该电池，并以N-甲酰基吡咯烷和4-叔丁基甲苯的甲氧基化反应为例说明了其在电合成中的应用。结果表明，该反应可以一次完成，转化率高。如上所述，该装置允许生产几个摩尔/小时的甲氧基化产物。(C)2011爱思唯尔有限公司。保留所有权利。
A single channel microfluidic electrolysis cell based on inexpensive materials and fabrication techniques is described. The cell is characterised using the electrochemistry of the Fe(CN)(6)(3-)/Fe(CN)(6)(4-) couple and its application in electrosynthesis is illustrated using the methoxylation reactions of N-formylpyrrolidine and 4-t-butyltoluene. It is shown that the reactions can be carried out with a good conversion in a single pass. The device, as described, allows the production of several mmol/hour of the methoxylated products. (C) 2011 Elsevier Ltd. All rights reserved.