Subcritical solvothermal synthesis of condensed inorganic materials.

Subcritical solvothermal synthesis of condensed inorganic materials.
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DOI:
10.1039/b105762f
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发表时间:
2002-06
影响因子:
46.2
通讯作者:
R. Walton
R. Walton
中科院分区:
化学1区
文献类型:
--
作者:
R. Walton

文献摘要

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溶剂热法最近已经从沸石合成扩展到形成凝聚的无机固体,其由于诸如离子导电性、固态磁性、巨磁阻、低热膨胀和铁电性的性质而在不同领域中找到用途。这提供了特定的优势,在传统的陶瓷合成路线,无机固体和这些突出的例子,从最近的文献中,和努力集中在确定固体的形成机制,从用于溶剂热程序的非均相混合物进行了讨论。
The solvothermal method has recently been extended from zeolite synthesis to the formation of condensed inorganic solids, which find uses in diverse areas due to properties such as ionic-conductivity, solid-state magnetism, giant magnetoresistance, low thermal expansion and ferroelectricity. This offers specific advantages over the traditional ceramic synthetic routes to inorganic solids and these are highlighted with examples from the recent literature, and the efforts focussed on determining the formation mechanism of solids from the heterogeneous mixtures used in solvothermal procedures are discussed.