Evaluation of carbon nanopores using large molecular probes in grand canonical Monte Carlo simulations and experiments
Evaluation of carbon nanopores using large molecular probes in grand canonical Monte Carlo simulations and experiments
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DOI：
10.1016/j.carbon.2015.02.077
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发表时间：
2015-07-01
期刊：
影响因子：
10.9
通讯作者：
Iijima, Sumio
中科院分区：
文献类型：
--
作者：
Ohba, Tomonori;Yamamoto, Shotaro;Iijima, Sumio
纳米孔(孔径在1-5 nm之间)一直是人们关注的对象，因为它们可以选择性地吸附相对较大的分子，如大分子和聚合物分子。传统的分析孔结构的方法--如77K下的N-2吸附测量--可以用来研究微孔和介孔结构，但缺乏对纳米孔或微孔之间边界的研究(
Nanopores (pores between 1 and 5 nm) have been the object of a great deal of attention because they can selectively adsorb relatively large molecules such as macromolecules and polymer molecules. Conventional methods for analyzing porous structures-such as N-2 adsorption measurements at 77 K can be used to investigate microporous and mesoporous structures, but there is a lack of investigation of nanopores or the boundary between micropores (