Carbon Quantum Dots Decorated C3N4/TiO2 Heterostructure Nanorod Arrays for Enhanced Photoelectrochemical Performance

Carbon Quantum Dots Decorated C3N4/TiO2 Heterostructure Nanorod Arrays for Enhanced Photoelectrochemical Performance
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碳量子点修饰的 C3N4/TiO2 异质结构纳米棒阵列可增强光电化学性能

DOI:
10.1149/2.1281707jes
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发表时间:
2017-06
影响因子:
3.9
通讯作者:
Zhang Yue
Zhang Yue
中科院分区:
工程技术4区
文献类型:
--
作者:
Wei Qingyi;Yan Xiaoqin;Kang Zhuo;Zhang Zheng;Cao Shiyao;Liu Yichong;Zhang Yue

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TiO 2 is a commonly employed material for photoelectrochemical (PEC) solar water splitting due to its nontoxicity, abundance and great stability. However, TiO 2 suffers from low PEC efficiency because of the weak absorption of visible light. Here, carbon quantum dots decorated C 3 N 4/TiO 2 heterostructure nanorod arrays (CQDs/C 3 N 4/TiO 2 NAs) were designed and fabricated to solve this shortcoming. The CQDs/C 3 N 4/TiO 2 NAs exhibit an increased solar to hydrogen conversion efficiency which is 5.8 times that of TiO 2 NAs and excellent stability in strong alkaline electrolyte. The enhanced performance of the CQDs/C 3 N 4/TiO 2 NAs is attributed to the improved light absorption and charge separation and transfer induced by the C 3 N 4 and CQDs. This work provides a promising approach for the design of low cost and environmentally friendly photoanodes for efficient and stable PEC applications.
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