Application of named reactions in polymer synthesis
Application of named reactions in polymer synthesis
复制标题
DOI：
10.1007/s11426-015-5447-1
复制
发表时间：
2015-06
期刊：
影响因子：
--
通讯作者：
Xue Jiang;Chun Feng;Guolin Lu;Xiaoyu Huang
中科院分区：
文献类型：
--
作者：
Xue Jiang;Chun Feng;Guolin Lu;Xiaoyu Huang
近年来，随着高分子科学的迅速发展，经典命名反应的应用已从小分子化合物转移到高分子上。所述反应在单体选择、溶剂环境、反应温度和后修饰方面的多功能性允许在其它反应过程不起作用的条件下合成复杂的大分子结构。本文将高分子链合成中的命名反应分为过渡金属催化的交叉偶联反应、无金属催化的交叉偶联反应和多组分反应三类。因此，我们着重讨论了这些命名反应在高分子合成中的应用进展
In recent years, with the rapid development of polymer science, the application of classical named reactions has transferred from small-molecule compounds to polymers. The versatility of named reactions in terms of monomer selection, solvent envi-ronment,reaction temperature, and post-modification permits the synthesis of sophisticated macromolecular structures under conditions where other reaction processes will not operate. In this review, we divided the named reactions employed in polymer-chain synthesis into three types: transition metal-catalyzed cross-coupling reactions, metal-free cross-coupling reactions,and multi-components reactions. Thus, we focused our discussion on the progress in the utilization of these named reactionsin polymer synthesis