Formic acid: a future bridge between the power and chemical industries
Formic acid: a future bridge between the power and chemical industries
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DOI：
10.1039/c5gc00249d
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发表时间：
2015-05
期刊：
影响因子：
9.8
通讯作者：
W. Supronowicz;I. Ignatyev;G. Lolli;A. Wolf;L. Zhao;L. Mleczko
中科院分区：
文献类型：
--
作者：
W. Supronowicz;I. Ignatyev;G. Lolli;A. Wolf;L. Zhao;L. Mleczko
在未来的氢经济中，甲酸被认为是一种高效的储氢分子，是化学工业的新的C1构件。甲酸可以作为一种可持续的一氧化碳来源。在本工作中，找到了甲酸及其衍生物分解为一氧化碳的有效催化剂。所建议的催化剂是广泛可用的沸石，使该工艺在工业规模应用上是可行的。因此，甲酸及其衍生物可以被视为一氧化碳的液体和可储存版本，可以直接用于现有的化学价值链。
In the future hydrogen economy, formic acid is considered an efficient hydrogen storage molecule and a new C1 building block for the chemical industry. Formic acid could be used as a sustainable carbon monoxide source. In the present work efficient catalysts for the decomposition of formic acid and its derivatives to carbon monoxide have been found. The proposed catalysts are widely available zeolites, making the process feasible for industrial scale applications. Thus, formic acid and its derivatives could be seen as liquid and storable versions of carbon monoxide, which could be directly used in the existing chemical value chain.