Synthesis of new copper(i) based linear 1-D-coordination polymers with neutral imidazolinium-dithiocarboxylate ligands
Synthesis of new copper(i) based linear 1-D-coordination polymers with neutral imidazolinium-dithiocarboxylate ligands
复制标题
具有中性咪唑啉鎓-二硫代羧酸盐配体的新型铜(i)基线性一维配位聚合物的合成
DOI：
10.1039/c4ra09033k
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发表时间：
2015
期刊：
影响因子：
3.9
通讯作者：
R. Wilhelm
中科院分区：
文献类型：
--
作者：
A. Neuba;J. Ortmeyer;D. D. Konieczna;G. Weigel;U. Flörke;G. Henkel;R. Wilhelm
咪唑啉二硫代羧酸甜菜碱首次被用作与卤化铜(I)的配位聚合物中的配体。所得一维配位化合物显示出具有三角配位铜(I)的线性双链结构。探索了该材料作为异质光催化剂的潜力。
An imidazolinium-dithiocarboxylate betaine has been applied for the first time as a ligand in a coordination polymer with copper(I) halides. The resulting 1-D-coordination compounds show a linear double chain structure with trigonally coordinated copper(I). The potential of the material as a heterogeneous photocatalyst was explored.