Ground and electronically excited singlet-state structures of 5-fluoroindole deduced from rotationally resolved electronic spectroscopy and ab initio theory.

Ground and electronically excited singlet-state structures of 5-fluoroindole deduced from rotationally resolved electronic spectroscopy and ab initio theory.
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从旋转分辨电子光谱和从头算理论推导出 5-氟吲哚的基态和电子激发单线态结构

DOI:
10.1002/cphc.201200345
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发表时间:
2012
期刊:
Chemphyschem : a European journal of chemical physics and physical chemistry
影响因子:
--
通讯作者:
Schmitt
Schmitt
中科院分区:
--
文献类型:
--
作者:
Oeltermann;Tatchen;Schmitt

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利用5FI的无振动电子源旋转分辨光谱测定了5 -氟吲哚(5FI)的电子基态和最低激发单重态(S1)的结构和电子性质。根据轴向重定向哈密顿量参数,确定了分子框架中跃迁偶极矩的绝对取向,确定了激发态的性质为Lb。
The structure and electronic properties of the electronic ground state and the lowest excited singlet state (S1) of 5‐fluoroindole (5FI) were determined by using rotationally resolved spectroscopy of the vibration‐less electronic origin of 5FI. From the parameters of the axis reorientation Hamiltonian, the absolute orientation of the transition dipole moment in the molecular frame was determined and the character of the excited state was identified as Lb.
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