ent-Kaurane Diterpenes and Further Constituents from Wedelia trilobata

ent-Kaurane Diterpenes and Further Constituents from Wedelia trilobata
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来自三叶蟛蜞菊的对映贝壳杉烷二萜和其他成分

DOI:
10.1002/hlca.201000301
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发表时间:
2011-05-01
影响因子:
1.8
通讯作者:
Gao, Kun
Gao, Kun
中科院分区:
化学4区
文献类型:
--
作者:
Qiang, Yin;Du, Dao-Lin;Gao, Kun

文献摘要

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从三叶委陵菜地上部分分离得到两个新的胡萝卜素A(8)和B(9),以及其他18个化合物,包括倍半萜1和2、胡萝卜烷二萜3-7、三萜类10和11、甾体12-14、黄酮类15-17以及苯衍生物18-20。化合物A(8)和B(9)的结构通过广泛的光谱分析(包括UV、IR、核磁共振和MS)得到确证。化合物2和3的结构经X-射线单晶衍射法确证。
Two new ent-kaurane diterpenes, wedelidins A (8) and B (9), together with eighteen other constituents, including the sesquiterpenoids 1 and 2, ent-kaurane diterpenes 3 - 7, triterpenoids 10 and 11, steroids 12 - 14, and flavonoids 15 - 17 as well as benzene derivatives 18 - 20, were isolated from the aerial parts of Wedelia trilobata. The structures of wedelidins A (8) and B (9) were elucidated by extensive spectroscopic analyses (including UV, IR, NMR, and MS). Furthermore, the structures of compounds 2 and 3 were confirmed by X-ray single-crystal diffraction analyses.