The rhodium-catalyzed Pauson-Khand reaction
The rhodium-catalyzed Pauson-Khand reaction
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DOI：
10.1016/s0022-328x(00)00835-4
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发表时间：
2001-04-01
影响因子：
2.3
通讯作者：
Narasaka, K
中科院分区：
文献类型：
--
作者：
Kobayashi, T;Koga, Y;Narasaka, K
铑羰基配合物[RhCl(CO)(2)](2)是分子内和分子间Pauson-Khand反应的催化剂。使用铑催化剂，在CO的一臂下，由各种1,6-和1,7-炔制备环戊酮衍生物。并且，铑催化的反应通过将CO的分压降低到小于1atm而加速。(C) 2001 Elsevier Science B.V.版权所有
A rhodium carbonyl complex, [RhCl(CO)(2)](2), serves as a catalyst of the intra- and inter-molecular Pauson-Khand reaction. By the use of the rhodium catalyst, cyclopentenone derivatives are prepared from various 1,6- and 1,7-enynes under 1 arm of CO. Furthermore, this rhodium-catalyzed reaction is accelerated by reducing partial pressure of CO to less than 1 atm. (C) 2001 Elsevier Science B.V. All rights reserved.