Complexes of Eu(III)(hfa)3 with a planar chiral P(III) ligand (Phanephos): solvent-sensitive sign inversion of circularly polarised luminescence
Complexes of Eu(III)(hfa)3 with a planar chiral P(III) ligand (Phanephos): solvent-sensitive sign inversion of circularly polarised luminescence
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DOI：
10.1039/c7dt00741h
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发表时间：
2017-04-28
影响因子：
4
通讯作者：
Imai, Yoshitane
中科院分区：
文献类型：
--
作者：
Kono, Yuki;Hara, Nobuyuki;Imai, Yoshitane
Eu（III）（hfa）（3）与C-2对称平面P（III）配体的配合物由于D-5（0）-> F-7（1）和D-5（0）-> F-7（2）跃迁而表现出强烈的圆偏振发光（CPL），CPL信号的符号和形状取决于溶剂（丙酮或氯仿）的选择。
Complexes of Eu(III)(hfa)(3) with a C-2-symmetric planar P(III) ligand exhibited intense circularly polarised luminescence (CPL) due to D-5(0) -> F-7(1) and D-5(0) -> F-7(2) transitions, with the signs and shapes of CPL signals depending on the choice of solvent (acetone or chloroform).