Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles
Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles
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DOI：
10.1002/anie.201713324
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发表时间：
2018-03-26
影响因子：
16.6
通讯作者：
Marek, Ilan
中科院分区：
文献类型：
--
作者：
Dian, Longyang;Marek, Ilan
在（R，S）- josiphos的存在下，通过不对称铑催化非手性非官能化环丙烯衍生物与市售芳基硼酸进行芳基化反应，得到了多种高度非对映体和对映体富集的芳基环丙烷。
A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.