Radical chemistry of tin

Radical chemistry of tin
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锡的自由基化学

DOI:
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发表时间:
1998
期刊:
影响因子:
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通讯作者:
A. G. Davies
A. G. Davies
中科院分区:
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文献类型:
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作者:
A. G. Davies

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近年来,有机锡化合物的自由基反应,特别是涉及中间中性三烷基锡自由基R3Sn的自由基反应引起了人们的广泛关注。均溶反应的重要类型有
Free radical reactions of organotin compounds, particularly those which involve intermediate neutral trialkyltin radicals, R3Sn, have attracted a lot of attention in recent years. The important types of homolytic reactions are The formation and reactions of tin-centred radicals, RnSnX3-n. Homolytic reactions which occur at a ligand in an organotin compound. Bimolecular homolytic substitution at the tin centre in tin (IV) compounds RnSnX4-n. Electron transfer reactions to generate the radical cations, RnSnX4-n+, or anions, RnSnX4-n, and the subsequent reactions of these species.