From olefin to alkane metathesis: A historical point of view
From olefin to alkane metathesis: A historical point of view
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DOI：
10.1002/anie.200602155
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发表时间：
2006-01-01
影响因子：
16.6
通讯作者：
Thivolle-Cazat, Jean
中科院分区：
文献类型：
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作者：
Basset, Jean-Marie;Coperet, Christophe;Thivolle-Cazat, Jean
在过去的一个世纪里，烷烃转化一直是石油化工研究的主要焦点，[1-3]事实上，Banks和Bailey在负载MoO3或WO3体系上发现烯烃复分解是对烷烃和烯烃混合物在这类催化剂上的反应性进行研究的结果。[4,5]在这些条件下，只有烯烃被转化，这导致了非常重要的工业工艺的发展，如LummusABB工艺，它通过在w基催化剂上与2-丁烯交叉反应将乙烯转化为丙烯这一发现首先被Banks （philips）和Hughes (Chevron)[7,8]迅速转化为烷烃转化过程，他们将非均相脱氢/加氢和烯烃复分解催化剂结合在一起，使给定的烷烃可以转化为其低级和高级同系物。这个反应
Alkane conversion has been a major focus of petrochemical research for the past century,[1–3] and in fact the discovery of olefin metathesis on supported MoO3 or WO3 systems by Banks and Bailey was the result of the investigation of the reactivity of alkane and olefin mixtures on such types of catalysts.[4, 5] Under these conditions, only olefins were transformed, which led to the development of very important industrial processes such as the LummusABB process, which converts ethylene into propylene through cross-metathesis with 2-butenes on W-based catalysts.[6] This discovery was rapidly turned into an alkane conversion process first by Banks (Philipps) and then by Hughes (Chevron)[7, 8] by combining heterogeneous dehydrogenation/hydrogenation and olefin metathesis catalysts, which allows a given alkane to be converted into its lower and higher homologues. This reaction