Triaqua-(1,10-phenanthroline-2,9-dicarboxyl-ato)cobalt(II) dihydrate.
Triaqua-(1,10-phenanthroline-2,9-dicarboxyl-ato)cobalt(II) dihydrate.
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DOI：
10.1107/s1600536810007567
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发表时间：
2010-03-06
期刊：
影响因子：
--
通讯作者：
Gu JZ
中科院分区：
文献类型：
--
作者：
Shi ZF;Gao ZQ;Gu JZ
The title compound, [Co(C14H6N2O4)(H2O)3]·2H2O, has twofold crystallographic symmetry. The CoII atom is in a distorted pentagonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxylate ligand and one O atom from a water molecule forming the pentagonal plane, and two O atoms from two water molecules occupying axial positions. In the crystal, adjacent molecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network.
