Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework
Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework
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DOI：
10.1016/j.chemphys.2013.08.010
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发表时间：
2013-12-12
期刊：
影响因子：
2.3
通讯作者：
Morris, Russell E.
中科院分区：
文献类型：
--
作者：
Brown, Craig M.;Ramirez-Cuesta, Anibal Javier;Morris, Russell E.
用中子粉末衍射法测定了Ni-2（dobdc）（dobdc（4）= 2，5-二氧代-1，4-苯二甲酸酯）的结构与氘吸附的关系。关于氢在每个站点的本地吸附潜力的详细信息也被探测使用非弹性中子散射技术。这些结果进行了比较，以前发表的同构类似物和Ni 2+的变体显示了最短的氘-金属距离的M-2（dobdc）系列（M =镁，锌，钴，铁），迄今为止已经研究。由爱思唯尔公司出版
The structure of Ni-2(dobdc) (dobdc(4) = 2,5-dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogs and the Ni2+ variant shows the shortest deuterium-metal distance in the M-2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far. Published by Elsevier B.V.