S-F and S-C activation of SF6 and SF5 derivatives at rhodium: conversion of SF6 into H2S.
S-F and S-C activation of SF6 and SF5 derivatives at rhodium: conversion of SF6 into H2S.
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DOI：
10.1002/anie.201308254
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发表时间：
2014-03
影响因子：
--
通讯作者：
Lada Zámostná;T. Braun;B. Braun
中科院分区：
文献类型：
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作者：
Lada Zámostná;T. Braun;B. Braun
本文报道了在[{Rh（μ-H）（dippp）}2]作用下，SF_6和SF_5有机化合物的S-F和S-C键活化反应。氟和硫醇物种被确定为产品或中间体，并通过X-射线衍射分析和多核NMR光谱进行了表征。开发了一种前所未有的将强效温室气体SF6转化为H2S的循环过程。
The degradation of SF6 and SF5 organyls by S-F and S-C bond-activation reactions at [{Rh(μ-H)(dippp)}2] under mild conditions is reported. Fluorido and thiolato species were identified as products or intermediates, and were characterized by X-ray diffraction analysis and multinuclear NMR spectroscopy. An unprecedented cyclic process for the conversion of the potent greenhouse gas SF6 into H2S was developed.